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Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones
Journal article

Silicon-directed Norrish type I cleavage of β-trimethylsilyl cycloalkanones

Jih Ru Hwu, Bryant A. Gilbert, Lung Ching Lin and Ben Ruey Liaw
Journal of the Chemical Society, Chemical Communications, (2), pp.161-163
1990

Abstract

The Me 3 Si group in β-trimethylsilyl cycloalkanones was able to direct the Norrish type I cleavage by providing regioselectivity in the C-1-C-2 bond cleavage and by increasing the quantum yield and the reaction rate.

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