Abstract
Dewetting of polymer thin films triggered by thermal or solvent annealing on flat substrates have been widely studied. Research on dewetting of polymer thin films on curved substrate, however, has been rarely investigated and remains a great challenge, especially for dewetting induced by solvent annealing. In this work, we study the dewetting of polymer thin films on curved substrates by annealing poly(methyl methacrylate) (PMMA) nanotubes in cylindrical nanopores of anodic aluminum oxide (AAO) templates via dimethylformamide (DMF) vapor treatment. After solvent annealing, dewetting of the curved PMMA thin films is induced, resulting in the formation of porous PMMA nanotubes. By changing the experimental conditions such as annealing time, solvent quality, and molecular weight of polymer, the hole sizes of the PMMA nanotubes can be controlled or even prevented. To demonstrate the universality of this method, porous nanotubes of polystyrene (PS) and fluorescent pyrene-ended PMMA (Py-PMMA) are also fabricated. This work not only provides a better understanding of dewetting of polymer thin films on curved substrates but also offers a promising new way to prepare porous polymer nanotubes with controllable hole sizes.