摘要
Two new coordination polymers, [Ni(H 2 O)(BDC)(bpp)] n (1) and [Co(mBDC)(bpp)] n (2) (BDC = 1,4-benzene dicarboxylate anion; bpp = 4,4′-trimethylene dipyridine; mBDC = 1,3-benzene dicarboxylate anion), were synthesized by solvothermal reaction and structurally characterized. Single crystal X-ray diffraction showed that 1 consists of an inclined interpenetration of 1D nets generating an overall 3D entanglement and compound 2 of 1D chains. The luminescent and magnetic properties of both compounds in the solid state were also investigated. Crystal data: 1: orthorhombic, Pnna; a = 18.3648(6), b = 13.6854(4), c = 16.2307(5) Å, V = 4079.3(2) Å 3 , and Z = 8. Crystal data: 2: triclinic, P1̄; a = 8.6966(4), b = 10.1093(4), c = 11.8334(4) Å, α = 68.263(1)°, β = 82.895(1)°, γ = 78.370(1)°, V = 945.16(7) Å 3 , and Z = 2. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.