Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

Yu-Lun Huang; Duan-Yen Lu; Hsien-Cheng Yu; Jen-Shiang K. Yu; Chia-Wei Hsu; Ting-Shen Kuo; Gene-Hsiang Lee; Yu Wang; Yi-Chou Tsai

doi:10.1002/anie.201202337

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

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Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

Yu-Lun Huang, Duan-Yen Lu, Hsien-Cheng Yu, Jen-Shiang K. Yu, Chia-Wei Hsu, Ting-Shen Kuo, Gene-Hsiang Lee, Yu Wang 和 Yi-Chou Tsai

Angewandte Chemie - International Edition, 卷.51(31), 頁碼.7781-7785

07/2012

DOI: https://doi.org/10.1002/anie.201202337

PMID: 22730058

摘要

amidinate

axial coordination

chromium

formation mechanism

quintuple bonds

Chemistry (all)

Catalysis

Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr ^I and Cr ^II ), which are important species in the formation of type I quintuple-bonded complexes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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題名: Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination
翻譯題名: Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination
創作者：: Yu-Lun Huang (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Duan-Yen Lu (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Hsien-Cheng Yu (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Jen-Shiang K. Yu (作者) - Institute of Bioinformatics and Systems Biology
Chia-Wei Hsu (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Ting-Shen Kuo (作者) - National Taiwan Normal University
Gene-Hsiang Lee (作者) - National Taiwan University
Yu Wang (作者) - National Taiwan University
Yi-Chou Tsai (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
學術資源類型: 期刊文章
出版日期: 07/2012
出版資訊: Angewandte Chemie - International Edition, 卷.51(31), 頁碼.7781-7785
語言: 英語

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

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