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Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination
Journal article   Peer reviewed

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination

Yu-Lun Huang, Duan-Yen Lu, Hsien-Cheng Yu, Jen-Shiang K. Yu, Chia-Wei Hsu, Ting-Shen Kuo, Gene-Hsiang Lee, Yu Wang and Yi-Chou Tsai
Angewandte Chemie - International Edition, Vol.51(31), pp.7781-7785
27/07/2012

Abstract

amidinate axial coordination chromium formation mechanism quintuple bonds
Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr I and Cr II ), which are important species in the formation of type I quintuple-bonded complexes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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