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Stereoselective synthesis of Neu5Acα(2→5)Neu5Gc: The building block of oligo/poly(→5-OglycolylNeu5Gcα2→) chains in sea urchin egg cell surface glycoprotein
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Stereoselective synthesis of Neu5Acα(2→5)Neu5Gc: The building block of oligo/poly(→5-OglycolylNeu5Gcα2→) chains in sea urchin egg cell surface glycoprotein

Gang-Ting Fan, Chen-Chang Lee, Chun-Cheng LinJim-Min Fang
Journal of Organic Chemistry, 卷.67(21), 頁碼.7565-7568
10/2002
PMID: 12376000

摘要

Organic Chemistry
The synthesis of a sialic acid dimer derivative, Neu5Acα(2→5)Neu5Gc, is described. The synthetic strategy is based on the use of allyl alcohol to achieve an exclusive α-sialylation product. The allyloxy group is also a latent glycolic acid that provides the subsequent coupling with neuraminate with minimal protection - deprotection manipulations.

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