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Studies on the electronic and vibrational states of colloidal CdSe/ZnS quantum dots under high pressures
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Studies on the electronic and vibrational states of colloidal CdSe/ZnS quantum dots under high pressures

C.T. Yuan, Y.C. Lin, Y.N. Chen, Q.L. Chiu, W.C. Chou, D.S. Chuu, W.H. Chang, H.S. Lin, R.C. RuaanC.M. Lin
Nanotechnology, 卷.18(18), 185402
05/2007

摘要

Bioengineering Chemistry (all) Materials Science (all) Mechanics of Materials Mechanical Engineering Electrical and Electronic Engineering
The electronic and vibrational states of colloidal core/shell CdSe/ZnS quantum dots are studied at room temperature by using high pressure optical measurements. Pressure-induced quadratic variations of lattice constants can be observed clearly from both photoluminescence (PL) and Raman spectra up to ∼7 GPa. This quadratic relationship is consistent with the theoretical prediction. The pressure coefficients of linear and quadratic terms are 32 meV GPa -1 , -1 meV GPa -2 for PL and 4.2 cm -1 GPa -1 , -0.1 cm -1 GPa -2 for Raman measurements, respectively. © 2007 IOP Publishing Ltd.

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