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Super High-k Dielectric via Composition-Dependent Hafnium Zirconium Oxide Superlattice for Si Nanosheet Gate-All-Around Field-Effect Transistors with NH3 Plasma-Optimized Interfaces
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Super High-k Dielectric via Composition-Dependent Hafnium Zirconium Oxide Superlattice for Si Nanosheet Gate-All-Around Field-Effect Transistors with NH3 Plasma-Optimized Interfaces

Yi-Ju Yao, Yu-Min Fu, Yu-Hung Chen, Chen-You Wei, Kai-Ting Huang, Guang-Li Luo, Fu-Ju Hou, Yu-Sheng LaiYung-Chun Wu
Materials, 卷.18(8), 頁.1740
10/04/2025
PMID: 40333395

摘要

Chemistry Chemistry, Physical Materials Science Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Technology
This paper presents an advanced dielectric engineering approach utilizing a composition-dependent hafnium zirconium oxide (Hf1-xZrxO2) superlattice (SL) structure for Si nanosheet gate-all-around field-effect transistors (Si NSGAAFETs). The dielectric (DE) properties of solid solution (SS) and SL Hf1-xZrxO2 capacitors were systematically characterized through capacitance-voltage (C-V) and polarization-voltage (P-V) measurements under varying annealing conditions. A high dielectric constant (k-value) of 59 was achieved in SL-Hf0.3Zr0.7O2, leading to a substantial reduction in equivalent oxide thickness (EOT). Furthermore, the SL-Hf0.3Zr0.7O2 dielectric was integrated into Si NSGAAFETs, with the interfacial layer (IL) further optimized via NH3 plasma treatment. The resulting devices exhibited superior electrical performance, including an enhanced ON-OFF current ratio (I-ON/I-OFF) reaching 10(7), an increased drive current, and significantly reduced gate leakage. These results highlight the potential of SL-Hf0.3Zr0.7O2 as a high-k dielectric solution for overcoming EOT scaling challenges in advanced CMOS technology and enabling further innovation in next-generation logic applications.

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