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Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex
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Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex

Abhijit Pal, Sarat Chandra Kumar, Ayon Kanti Ghosh, Chia-Her Lin, Eric Rivière, Talal Mallah 和 Rajarshi Ghosh
Polyhedron, 卷.110, 頁碼.221-226
05/2016
DOI: https://doi.org/10.1016/j.poly.2016.03.012

摘要

Catecholase activity Magnetism Michaelis-Menten kinetics Schiff base Trinuclear nickel(II) Physical and Theoretical Chemistry Inorganic Chemistry Materials Chemistry
The synthesis and X-ray crystallographic characterization of one antiferromagnetically coupled trinuclear Ni(II) complex, [Ni 3 (L) 2 (OAc) 2 ] (1) [L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol], is reported. It effectively catalyses the oxidation of 3,5-ditertiarybutyl catechol to its corresponding quinone in methanol solvent. It follows Michaelis-Menten kinetics with a turnover number of 3.85 × 10 3 h -1 .

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