Synthesis and X-ray structure of a formylated octamolybdate cluster [(HCO)2(Mo8O28)]6-

Richard D. Adams; Walter G. Klemperer; Rai-Shung Liu

doi:10.1039/C39790000256

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Synthesis and X-ray structure of a formylated octamolybdate cluster [(HCO)2(Mo8O28)]6-

Richard D. Adams, Walter G. Klemperer and Rai-Shung Liu

Journal of the Chemical Society, Chemical Communications, (6), pp.256-257

1979

DOI: https://doi.org/10.1039/C39790000256

Abstract

Molecular Medicine

Reaction of formic acid with aqueous (NH ₄ ) _6- [Mo ₇ O ₂₄ ]yields the compound (NH ₄ ) ₃ [(HCO)(Mo ₄ O ₁₄ )]·H ₂ O which has been shown by X-ray crystallography to contain the discrete [(H ₂ Mo ₈ O ₂₈ )] ^6- anion; this anion is related to the [H ₂ Mo ₈ O ₂₈ ] ^6- anion by replacement of its surface-bound protons with formyl groups.

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Title: Synthesis and X-ray structure of a formylated octamolybdate cluster [(HCO)2(Mo8O28)]6-
Creators - without role: Richard D. Adams - Yale University
Walter G. Klemperer - Columbia University
Rai-Shung Liu - Columbia University
Identifiers: 9957773756006774
Academic Unit: Department of Chemistry, College of Science, National Tsing Hua University
Language: English
Resource Type: Journal article
Publication Details: Journal of the Chemical Society, Chemical Communications, (6), pp.256-257

Synthesis and X-ray structure of a formylated octamolybdate cluster [(HCO)2(Mo8O28)]6-

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