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Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]
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Synthesis, crystal structure and catecholase activity of [Co(SCN)2(L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine]

Ashis Kumar Maji, Sumitava Khan, Ayon Kanti Ghosh, Chia -Her Lin, Barindra Kumar Ghosh 和 Rajarshi Ghosh
Journal of Molecular Structure, 卷.1143, 頁碼.489-494
09/2017
DOI: https://doi.org/10.1016/j.molstruc.2017.04.105

摘要

Catecholase activity Cobalt Schiff base X-ray structure Analytical Chemistry Spectroscopy Organic Chemistry Inorganic Chemistry
Synthesis and structural characterization of a mononuclear cobalt(II) complex [Co(SCN) 2 (L)] [L = N,N′-(bis(pyridine-2-yl)benzilidene)-1,2-ethanediamine] (1) is reported. Molecular geometry of the complex is found to be distorted octahedron with CoN 4 S 2 chromophore. 1 is shown to respond in catecholase activity in methanol and acetonitrile. In each solvent Michaelis-Menten reaction kinetics were followed. The reaction mechanism of the catecholase activity is investigated using mass spectrometry.

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