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Synthesis of Fucopeptides as Sialyl Lewis X Mimetics
期刊文章

Synthesis of Fucopeptides as Sialyl Lewis X Mimetics

S.-H. Wu, M. Shimazaki, C.-C. Lin, L. Qiao, W. J. MoreeC.-H Wong
Angewandte Chemie, 卷.35(1), 頁.88
1996

摘要

Sialyl Lewis X Mimetics
The same biological activity as the antigen determinant sialyl Lewisx was shown by the fucopeptide 1 in a binding assay with E-selectin. In the design of this mimetic the type and spatial arrangement of the functional groups essential for the interaction between sialyl Lewisx and E-selectin were considered. Fucopeptide 1, which may have potential as an antiinflammatory agent, was synthesized from L-fucose. L-threonine, (2S,3R)-2-amino-3,4-dihydroxy-butyric acid, and glutarate.

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