Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets

Tse-An Chen; Rai-Shung Liu

doi:10.1002/chem.201101057

Back

Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets

Journal article

Open access

Peer reviewed

Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets

Tse-An Chen and Rai-Shung Liu

Chemistry - A European Journal, Vol.17(29), pp.8023-8027

11/07/2011

DOI: https://doi.org/10.1002/chem.201101057

Appears in keyword about Chemistry

Abstract

aromaticity

hydrocarbons

oxidation

synthetic methods

UV/Vis spectroscopy

A new synthesis of large polyaromatic hydrocarbons (PAHs) with low Clar sextets is reported (see figure). The synthetic protocol involves starting bis(biaryl)diynes, which undergo initial PtCl ₂ -catalyzed aromatizations, and subsequent 2,3-dichloro-5,6-dicyano benzoquinone (DDQ) oxidation. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Files and links (1)

url

https://doi.org/10.1002/chem.201101057View

Published (Version of record) Open

Metrics

1 Record Views

See more details

Details

Title: Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets
Creators - without role: Tse-An Chen - Department of Chemistry , National Tsing-Hua University
Rai-Shung Liu - Department of Chemistry , National Tsing-Hua University
Publication Details: Chemistry - A European Journal, Vol.17(29), pp.8023-8027
Identifiers: 9957766519906774
Academic Unit: Department of Chemistry, College of Science, National Tsing Hua University
Language: English
Resource Type: Journal article

Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets

Abstract

Files and links (1)

Related links

Metrics

Details

National Tsing Hua University Social media