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Synthetic and natural MOR zeolites as high-capacity adsorbents for the removal of nitrous oxide
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Synthetic and natural MOR zeolites as high-capacity adsorbents for the removal of nitrous oxide

Keita Yamashita, Zhendong Liu, Kenta Iyoki, Ching-Tien Chen, Shoko Miyagi, Yutaka Yanaba, Yusuke Yamauchi, Tatsuya OkuboToru Wakihara
Chemical Communications, 卷.57(11), 頁碼.1312-1315
02/2021
PMID: 33480896

摘要

Electronic Optical and Magnetic Materials Catalysis Ceramics and Composites Chemistry (all) Surfaces Coatings and Films Metals and Alloys Materials Chemistry
N 2 O is typically present as a trace gas in chemical processes, but its emission causes serious environmental issues. We herein demonstrate that ion-exchanged mordenite zeolites (framework code: MOR) can exhibit high capacities for N 2 O adsorption under ambient conditions. In particular, a natural MOR zeolite gives an adsorption capacity as high as 0.34 mmol-N 2 O per g-zeolite (1 atm, 25 °C), representing the best performing material among all zeolite-based adsorbents reported so far. The results contribute toward a comprehensive understanding of the structure-activity relationship and offer insights to establishing a zeolite-based adsorption system for enriching or removing N 2 O.

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