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The Spike in the C~6~0^ù^- ESR Spectrum: Oxygen Effect and Negative Temperature Dependence of the C~6~0O~2^ù^- Isomerization Rate
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The Spike in the C~6~0^ù^- ESR Spectrum: Oxygen Effect and Negative Temperature Dependence of the C~6~0O~2^ù^- Isomerization Rate

Yu Lien Hwang, Che Chau Yang 和 Kuo Chu Hwang
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 卷.101(43), 頁碼.7971-7976
1997

摘要

Biotechnology Chemistry Pharmaceutical Chemistry
A stable, broad ESR signal (g = 1.998, cap deltaH~p~p = 37.0 G) of the C~6~0^ù^- anion radical was generated by irradiation of a C~6~0-toluene solution in the presence of organic salt, [(ph)~3P]~2N^+(ph)~4B^-, and 14.3% methanol. Upon exposure to molecular oxygen, the broad band gradually diminishes and a narrow band of g = 2.0008 and cap deltaH~p~p = 3.32 G (hereafter, band b) grows, which further transforms to another narrow band of g = 2.0026 and cap deltaH~p~p = 1.67 G (hereafter, band c). The transformation rate of bands b to c was found to be negative temperature dependent, i.e., the higher the temperature, the slower the transformation rate. At high temperatures (e.g., 365 K) and in polar solvents (e.g., 30% methanol in toluene), band c can reversibly transform back to band b. Microwave power saturation experiments show that band c has much longer relaxation times than band b. Both bands b and c resemble the "spike" commonly observed in the C~6~0^ù^- anion radical ESR spectra and were designated to two isomers of the C~6~0O~2^ù^- anion radical. A kinetic model was derived to account for the negative temperature-dependent transformation rate of bands b to c.

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