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The effects of phenyltrimethoxysilane coupling agents on the properties of PTFE/silica composites
Journal article   Peer reviewed

The effects of phenyltrimethoxysilane coupling agents on the properties of PTFE/silica composites

Yung-Chih Chen, Hsueh-Chen Lin and YU-DER LEE
Journal of Polymer Research, Vol.11(1), pp.1-7
03/2004

Abstract

Composite Dielectric constant Polytetrafluoroethylene Printed circuit boards Properties Silane Silica
A study on PTFE reinforced with SiO 2 was described. This study included the manufactural process of SiO 2 -reinforced PTFE and the effects of the content of silane (Z6124) on the properties of the composites material, such as thermal, dielectric properties, tensile strength and morphology, etc. PTFE/silica composites of 60 wt% SiO 2 loaded with a different coupling agent content were mixed by a high-speed dispersion machine and prepared by a two-roll milling machine. Our results show that the sample treated with 3 wt% silane has the highest tensile strength and optimum dielectric properties. Furthermore, the tensile strength and coefficient of thermal expansion (CTE) increase, and the water absorption decreases, with an increasing silane content. These experiments reveal that silane treatment can reduce the overall hydrophilicity of the composites. Finally, predictions on dielectric and CTE properties are discussed. It has been found that experimental values of the dielectric constant agree well with those predicted by the rule of mixture.

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