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The physical mechanism on the threshold voltage temperature stability improvement for GaN HEMTs with pre-fluorination argon treatment
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The physical mechanism on the threshold voltage temperature stability improvement for GaN HEMTs with pre-fluorination argon treatment

Yun-Hsiang Wang, Yung C. Liang, Ganesh S. Samudra, Chih-Fang Huang, Wei-Hung KuoGuo-Qiang Lo
Applied Physics Letters, 卷.108(23), 233507
06/2016

摘要

Physics and Astronomy (miscellaneous)
In this paper, a normally-off AlGaN/GaN MIS-HEMT with improved threshold voltage (V TH ) thermal stability is reported with investigations on its physical mechanism. The normally-off operation of the device is achieved from novel short argon plasma treatment (APT) prior to the fluorine plasma treatment (FPT) on Al 2 O 3 gate dielectrics. For the MIS-HEMT with FPT only, its V TH drops from 4.2 V at room temperature to 0.5 V at 200 °C. Alternatively, for the device with APT-then-FPT process, its V TH can retain at 2.5 V at 200 °C due to the increased amount of deep-level traps that do not emit electrons at 200 °C. This thermally stable V TH makes this device suitable for high power applications. The depth profile of the F atoms in Al 2 O 3 , measured by the secondary ion mass spectroscopy, reveals a significant increase in the F concentration when APT is conducted prior to FPT. The X-ray photoelectron spectroscopy (XPS) analysis on the plasma-treated Al 2 O 3 surfaces observes higher composition of Al-F bonds if APT was applied before FPT. The enhanced breaking of Al-O bonds due to Ar bombardment assisted in the increased incorporation of F radicals at the surface during the subsequent FPT process. The Schrödinger equation of Al 2 O x F y cells, with the same Al-F compositions as obtained from XPS, was solved by Gaussian 09 molecular simulations to extract electron state distribution as a function of energy. The simulation results show creation of the deeper trap states in the Al 2 O 3 bandgap when APT is used before FPT. Finally, the trap distribution extracted from the simulations is verified by the gate-stress experimental characterization to confirm the physical mechanism described.

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