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The size effect of silver nanocubes on gap-mode surface enhanced Raman scattering substrate
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The size effect of silver nanocubes on gap-mode surface enhanced Raman scattering substrate

Kai-Wei Tsai, Kundan Sivashanmugan, Chen-Hsueh Lin, Po-Ju Tsai, Shu-Chun Cheng, Yung-Chiang Lan, Tsan-Yao ChenTen-Chin Wen
Journal of the Taiwan Institute of Chemical Engineers, 卷.69, 頁碼.146-150
12/2016

摘要

Melamine Nanocubes Plasmonic cavities Rhodamine 6 G Surface enhanced Raman scattering Chemistry (all) Chemical Engineering (all)
This study demonstrates the size effect of silver nanocubes with the namely dimension 50 and 70 nm atop the massed silver surface (denoted, 50-NcIM and 70-NcIM) on surface enhanced Raman scattering (SERS) by using rhodamine 6 G and melamine with the irradiation of 532, 633, and 780 nm lasers. In addition, the NcIM substrate was exhibited a strong SERS effect under 633 and 780 nm laser irradiation. The enhancement factors of 50-NcIM and 70-NcIM samples were reached nearly 10 9 and 10 8 , respectively. The simulation results show that plasmonic cavities (PC) derived from 50-NcIM and 70-NcIM respectively possess the stronger electromagnetic field density and the larger extended PC area under 633 and 780 nm laser irradiation, interpreting the experimental results well.

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