The zwitterion-accelerated [3,3]-sigmatropic rearrangement of allyl vinyl sulfoxided to sulfines. A specific class of charge-accelerated rearrangement

Jih Ru Hwu; Denise A Anderson

doi:10.1016/S0040-4039(00)85108-4

Back

The zwitterion-accelerated [3,3]-sigmatropic rearrangement of allyl vinyl sulfoxided to sulfines. A specific class of charge-accelerated rearrangement

Journal article

Peer reviewed

The zwitterion-accelerated [3,3]-sigmatropic rearrangement of allyl vinyl sulfoxided to sulfines. A specific class of charge-accelerated rearrangement

Jih Ru Hwu and Denise A Anderson

Tetrahedron Letters, Vol.27(41), pp.4965-4968

1986

DOI: https://doi.org/10.1016/S0040-4039(00)85108-4

Abstract

Conversion of allyl vinyl gulf oxides 5 and 8 to γ, δ-unsaturated sul fines 6 and 9, respectively, under neutral conditions shows that the accelerating effects of the charges in a zwitterionic moiety do not cancel, instead the sulfoxide functionality significantly facilitates the rearrangement. © 1986.

Metrics

1 Record Views

Details

Title: The zwitterion-accelerated [3,3]-sigmatropic rearrangement of allyl vinyl sulfoxided to sulfines. A specific class of charge-accelerated rearrangement
Creators - without role: Jih Ru Hwu - Johns Hopkins University
Denise A Anderson - Johns Hopkins University
Publication Details: Tetrahedron Letters, Vol.27(41), pp.4965-4968
Identifiers: 9957768493706774
Academic Unit: National Tsing Hua University
Language: English
Resource Type: Journal article

The zwitterion-accelerated [3,3]-sigmatropic rearrangement of allyl vinyl sulfoxided to sulfines. A specific class of charge-accelerated rearrangement

Abstract

Related links

Metrics

Details

National Tsing Hua University Social media