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Theory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes
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Theory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes

Duan-Yen Lu, Jen-Shiang K. Yu, Ting-Shen Kuo, Gene-Hsiang Lee, Yu Wang 和 Yi-Chou Tsai
Angewandte Chemie - International Edition, 卷.50(33), 頁碼.7611-7615
08/2011
DOI: https://doi.org/10.1002/anie.201102296
PMID: 21717546

摘要

cadmium manganese metal-metal interactions reaction mechanisms zinc Chemistry (all) Catalysis
Two Mni-Mn-bonded dimanganese complexes, as well as the tetracadmium complex shown in the picture, were obtained by reduction of [M 2 {η- 2 -Me 2 Si(NDipp) 2 } 2 ] (M=Mn, Cd; Dipp=2,6-iPr 2 C 6 H 3 ). Their structures are consistent with those of calculated intermediates in the reduction of [Zn 2 {η- 2 -Me 2 Si(NDipp) 2 } 2 ]. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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