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Thermal- and photo-induced transformations of N-aryl-N-nitroso-hydroxylamine ammonium salts to azoxy compounds
Journal article   Peer reviewed

Thermal- and photo-induced transformations of N-aryl-N-nitroso-hydroxylamine ammonium salts to azoxy compounds

Jih Ru Hwu, Chii Shyang Yau, Shwu-Chen Tsay and Tong-Ing Ho
Tetrahedron Letters, Vol.38(52), pp.9001-9004
29/12/1997

Abstract

Heating of an ethanolic solution containing N-aryl-N-nitrosohydroxylamine ammonium salts at 78°C produced the desired azoxy compounds in 80-93% yields. Furthermore, irradiation with UV light (κ ≤300 nm) of ethanolic solutions of those ammonium salts at room temperature also provided the desired azoxy compounds in 51-72% yields.

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