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Thermomigration suppression in Sn3.5Ag solder joints by hot-end FeCoNiMn alloy
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Thermomigration suppression in Sn3.5Ag solder joints by hot-end FeCoNiMn alloy

Yu-An Shen, Yun-Xuan Lin, Fan-Yi Ouyang, Hiroshi NishikawaMing-Hung Tsai
Intermetallics, 卷.154, 107821
03/2023

摘要

Interfacial reaction Lead-free solder Multielement alloy Multielement intermetallic compound Thermal stability Wettability Chemistry (all) Mechanics of Materials Mechanical Engineering Metals and Alloys Materials Chemistry
Temperature gradient is inevitable in solder joints in advanced electronic packaging; it induces thermomigration (TM), critically affecting the reliability of micro solder joints. Although a FeCoNiMn alloy (FCNM) can resist thermal aging in solder joints, its TM resistance has seldom been examined. Thus, this study investigated the TM in Cu/Sn3.5Ag (SA3.5)/FCNM solder joints between a cold end (50 °C) and a hot end (200 °C) at different times. A multielement intermetallic compound (MEIMC), (Cu, Mn, Fe, Co, Ni) 6 Sn 5 , is formed at the SA3.5/FCNM interface in the reflowed and aged solder joints. A (Fe, Co, Ni, Mn)Sn 2 MEIMC also formed, but it was very thin. The (Cu, Mn, Fe, Co, Ni) 6 Sn 5 was completely decomposed by TM from the hot-end FCNM. In contrast, the (Cu, Mn, Fe, Co, Ni) 6 Sn 5 MEIMC thickened as the rapid TM flux of Cu from the hot-end Cu cap; however, the low chemical flux from FCNM hindered its formation, which was replaced by Cu 6 Sn 5 formation near the Cu/SA3.5 interface. The findings demonstrate that FCNM providing a very low chemical flux is a remarkably promising diffusion barrier for TM in micro solder joints.

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