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Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]- into [(NO)2Fe(η3-HCS2)]- via reaction with CS2
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Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]- into [(NO)2Fe(η3-HCS2)]- via reaction with CS2

Huang-Chia Huang, Wei-Min Ching, Yu-Ting Tseng, Chien-Hong Chen 和 才德 魯
Dalton Transactions, 卷.48(18), 頁碼.5897-5902
04/01/2019
DOI: https://doi.org/10.1039/c8dt04714f

摘要

Bioinorganic Chemistry;Nitric Oxide;Metal-organic Framework;Inorganic Chemistry;Dinitrosyl Iron Complex Inorganic Chemistry

Reaction of compounds [(NO) 2 Fe(TMEDA)] and [BH 4 ] - affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO) 2 Fe(η 2 -BH 4 )] - (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS 2 into DNIC [(NO) 2 Fe(η 3 -HCS 2 )] - , the first DNIC featuring both linear/bent NO ligands and Fe 3d z 2 -to-HCS 2 π∗ backbonding interaction.

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