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Two-Dimensional (2D) Materials-Inserted Conductive Bridge Random Access Memory: Controllable Injection of Cations in Vertical Stacking Alignment of MoSe2 Layers Prepared by Plasma-Assisted Chemical Vapor Reaction
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Two-Dimensional (2D) Materials-Inserted Conductive Bridge Random Access Memory: Controllable Injection of Cations in Vertical Stacking Alignment of MoSe2 Layers Prepared by Plasma-Assisted Chemical Vapor Reaction

Ying-Chun Shen, Chung-Yu Chen, Ling Lee, Chun-Hsiu Chiang, Yu-Chieh Hsu, Ruei-Hong Cyu, Yu-Ren Peng, Yi-Jen Yu, Hao-Chung Kuo, Tseung-Yuen Tseng, …
ACS Materials Letters, 卷.5(5), 頁碼.1401-1410
05/2023

摘要

Chemical Engineering (all) Biomedical Engineering Materials Science (all)
Conductive bridge random access memories (CBRAMs) are one of the promising nonvolatile memories for the next generation of technology. The resistive switching behavior of CBRAMs relies on the formation and the rupture of the filaments in the switching layer by the cation injection from the active metal electrode. However, CBRAMs are suffered from an overinjection behavior of the cation, deteriorating the switching performance. In this regard, we developed the vertical alignment of the MoSe 2 (v-MoSe 2 ) layer by a plasma-assisted chemical vapor reaction to prevent the overmigration of the Cu species. With the insertion of the v-MoSe 2 layer, the Cu/v-MoSe 2 /TiO 2 /Pt device shows a Forming-free characteristic and low-operation voltage range, avoiding the overinjection of the Cu species and hard breakdown of the device. Besides, the identical pulse scheme was applied to characterize the synaptic function of devices, with which the improved endurance and the enhanced linearity of the resistance change during potentiation and depression can be achieved.

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