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Ultrahard and stable nanostructured cubic boron nitride from hexagonal boron nitride
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Ultrahard and stable nanostructured cubic boron nitride from hexagonal boron nitride

Hao Liang, Weitong Lin, Qiming Wang, Wei Zhang, Shixue Guan, Jiawei Zhang, Ji-Jung Kai, Duanwei HeFang Peng
Ceramics International
2020

摘要

Cubic boron nitride Dense defects Mechanical behavior Nanostructured Stability Electronic Optical and Magnetic Materials Ceramics and Composites Process Chemistry and Technology Surfaces Coatings and Films Materials Chemistry
Cubic boron nitride (cBN), a typical superhard material, has garnered significant interest for both fundamental scientific research and technical applications. Here, nanostructured cBN with high-density nanotwins and stacking faults was synthesized by rapid quenching using hexagonal boron nitride (hBN) as the starting material at a moderate temperature (2200 K) and low pressure (13 GPa). This synthetic nanostructured cBN exhibits high Vickers hardness (78 GPa), high fracture toughness (11.8 MPa·m ), and extremely high oxidization temperature (1565 K). We propose that the refined grain structure and excellent mechanical properties of the cBN synthesized in this study is attributed mainly to dislocation slips and (111) mechanical nanotwins that dominate this phase transformation.

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