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Unravelling the Mechanisms Behind Mixed Catalysts for the High Yield Production of Single-Walled Carbon Nanotubes
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Unravelling the Mechanisms Behind Mixed Catalysts for the High Yield Production of Single-Walled Carbon Nanotubes

Sailaja Tetali, Mujtaba Zaka, Ronny Schoenfelder, Alicja Bachmatiuk, Felix Boerrnert, Imad Ibrahim, Jarrn-Horng Lin, Gianaurelio Cuniberti, Jamie H. Warner, Bernd Buechner, …
ACS nano, 卷.3(12), 頁碼.3839-3844
22/12/2009
PMID: 19883094
Web of Science ID: WOS:000272846000013

摘要

Chemistry Chemistry, Multidisciplinary Chemistry, Physical Materials Science, Multidisciplinary Nanoscience & Nanotechnology Science & Technology Science & Technology - Other Topics Materials Science Physical Sciences Technology
The use of mixed catalysts for the high-yield production of single-walled carbon nanotubes is well-known. The mechanisms behind the Improved yield are poorly understood. In this study, we systematically explore different catalyst combinations from Ni, Co, and Mo for the synthesis of carbon nanotubes via laser evaporation, Our findings reveal that the mixing of catalysts alters the catalyst cluster size distribution, maximizing the clusters' potential to form a hemispherical cap at nucleation and, hence, form a single-walled carbon nanotube. This process significantly improves the single-walled carbon nanotube yields.

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