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Viscoelastic thin polymer films under transient residual stresses: Two-stage dewetting on soft substrates
Journal article   Peer reviewed

Viscoelastic thin polymer films under transient residual stresses: Two-stage dewetting on soft substrates

S. Al Akhrass, G. Reiter, S.Y. Hou, M.H. Yang, Y.L. Chang, F.C. Chang, C.F. Wang and A.C.-M. Yang
Physical Review Letters, Vol.100(17), 178301
28/04/2008

Abstract

A nonmonotonic, two-stage dewetting behavior was observed for spin coated thin viscoelastic polymer films on soft elastic substrates. At times shorter than the relaxation time of the polymer (t<τrep), dewetting generated deep trenches in the soft rubbery substrate which, in turn, almost stopped dewetting. At later stages (tτrep), dewetting accelerated, accompanied by an unstable rim. However, holes nucleated at t<τrep showed only this second-stage behavior. Our observations are attributed to large elastic deformations in the substrate caused by transient residual stresses within the film. © 2008 The American Physical Society.

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