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Visible-light-activated copper(i) catalyzed oxidative Csp-Csp cross-coupling reaction: Efficient synthesis of unsymmetrical conjugated diynes without ligands and base
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Visible-light-activated copper(i) catalyzed oxidative Csp-Csp cross-coupling reaction: Efficient synthesis of unsymmetrical conjugated diynes without ligands and base

Arunachalam Sagadevan, Ping-Chiang LyuKuo Chu Hwang
Green Chemistry, 卷.18(16), 頁碼.4526-4530
2016

摘要

Environmental Chemistry Pollution
A novel visible-light-promoted copper-catalysed process for the C sp -C sp cross-coupling reaction of terminal alkynes at room temperature is described. The current photochemical method is simple, highly functional group compatible, and more viable towards the construction of bio-active 1,3-unsymmetrical conjugated diynes without the need of bases/ligands, additives and expensive palladium/gold catalysts.

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