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Voltammetric Investigation of Platinum Oxides¾II. Effect of Hydration on Their Reduction Behavior
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Voltammetric Investigation of Platinum Oxides¾II. Effect of Hydration on Their Reduction Behavior

Chi-Chang HuKweun-Yo Liu
Electrochimica Acta Electrochimica Acta, 卷.45(19), 頁碼.3063-3068
2000

摘要

The reduction behavior of α platinum oxides on PtOx/Ti (fabricated by thermal decomposition) and Pt/Ti (reduced from PtOx/Ti) was compared using linear sweep voltammetry. The peak potential of α oxide reduction was found to shift to a less positive value with decreasing its hydration degree, which depended upon the lower potential limits and cycle number of cyclic voltammetry. Factors affecting the stability of various platinum oxides, including α and β types, were systematically discussed in this work.

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