Abstract
The microscopic process of abrasive wear and friction in glassy polymers was studied by using a special microscratch technique. A miscible blend of polystyrene (PS) and poly(phenylene oxide) (PPO) was used. It was found that as the composition varies there seems to exist two wear regimes in the blends controlled by different breakdown mechanisms corresponding to the brittle-ductile transition. Detailed study of the contact loads and SEM micrographs indicate that abrasive wear in the glassy polymers is controlled by microcracking under the asperity contacts. The critical load τ c for initiating microscopic cracks can be linked to the macroscopic wear via a statistical Weibull model where τ c is taken to be the mean of a strength distribution function. On the other hand, the friction coefficient was found to be independent of the composition but to vary strongly with the contact load. It approaches zero at the extrapolated zero load, but increases rapidly and eventually levels off with contact load. This behavior can be understood by a simple frictional adhesion model in which the polymer deformation during a frictional contact is analyzed by considering the compressive plastic ploughing and shearing yielding around the asperity contact. The shear strength S 0 of the polymer/asperity contacts was found to vary with the normal load. The vertical scratch hardness H v , which characterizes the spontaneous indentation yielding on the polymer surface, was found to be independent of scratch length and depth, and indeed can be regarded as a material constant. Although both S 0 and H v can accurately describe the frictional behavior of the glassy polymers, they bear no correlation to abrasive wear in the same materials. © 1997 John Wiley & Sons, Inc.