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White-light-emitting diodes based on blue and green quantum-confined CsPbBr3 perovskite quantum dots and red CdSe quantum dots without ion-exchange issues
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White-light-emitting diodes based on blue and green quantum-confined CsPbBr3 perovskite quantum dots and red CdSe quantum dots without ion-exchange issues

Che-Yu Chang, K.P.O. Mahesh, Ting-Qing Chen, Wei-Li Hong, Yu-Min Lin, Wei-Cheng Tseng, Wei-Sheng Chen, Ching-Ling Hsu, Sheng-Fu HorngYu-Chiang Chao
Journal of Materials Chemistry C
2023

摘要

Chemistry (all) Materials Chemistry
CsPbBr 3 quantum dots with various diameters around the Bohr exciton radius and emission wavelengths between 460 nm to 520 nm were prepared. Quantum dots with diameters of 4-13 nm were characterized via their absorption spectra, photoluminescence spectra, X-ray diffraction patterns, and time-resolved photoluminescence. Binary mixture solutions and composite films composed of blue and green CsPbBr 3 quantum dots showed two emission peaks without anion-exchange issues. A solution of red CdSe quantum dots was added to the sky-blue binary mixture solution to form a ternary mixture solution with white emission. Three clear emission peaks were observed, and the CIE chromaticity coordinates (0.33, 0.31) were obtained. A QD-polymer composite film with white emission was prepared and stacked on a UV LED to demonstrate white LEDs. Besides, white LEDs with a single emissive layer were prepared from the ternary mixture solution. Three emission peaks and CIE coordinates of (0.34, 0.33) were obtained.

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