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X-ray absorption study of ceria nanorods promoting the disproportionation of hydrogen peroxide
Journal article   Open access

X-ray absorption study of ceria nanorods promoting the disproportionation of hydrogen peroxide

Tai-Sing Wu, Yunyun Zhou, Renat F. Sabirianov, Wai-Ning Mei, Yun-Liang Soo and Chin Li Cheung
Chemical Communications, Vol.52(28), pp.5003-5006
2016

Abstract

A quasi in situ X-ray absorption study demonstrated that the disproportionation of hydrogen peroxide (H 2 O 2 ) promoted by ceria nanorods was associated with a reversible Ce 3+ /Ce 4+ reaction and structural transformations in ceria. The direction of this reversible reaction was postulated to depend on the H 2 O 2 concentration and the fraction of Ce 3+ species in ceria nanorods.
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https://doi.org/10.1039/c5cc10643eView
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