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ZnO-coated carbon nanotubes: Inter-diffusion of carboxyl groups and enhanced photocurrent generation
Journal article   Peer reviewed

ZnO-coated carbon nanotubes: Inter-diffusion of carboxyl groups and enhanced photocurrent generation

Chia-I Hung, Hua-Chiang Wen, Yao-Cheng Lai, Shih-Hsin Chang, Wu-Ching Chou and Wen-Kuang Hsu
ChemPhysChem, Vol.16(4), pp.812-816
16/03/2015

Abstract

carbon nanotubes defects nanostructures photocurrent zinc oxide
ZnO is a defect-governed oxide and emits light at both visible and UV regimes. This work employs atomic layer deposition to produce oxide particles on oxygenated carbon nanotubes, and the composites only show emission profiles at short wavelengths. The quenching of defect-related emissions at long wavelengths is verified, owing to carboxyl diffusion into oxygen vacancies, and doping is supported by ZnCO 3 formation in oxide lattice. Fully coated tubes display an increased photocurrent and the quantum efficiency increases by 22 % relative to the bare nanotubes.

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