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還原態觸媒的製備方法、其製備之還原態觸媒、其用途以及合成氣的製造方法
Patent

還原態觸媒的製備方法、其製備之還原態觸媒、其用途以及合成氣的製造方法

國立清華大學, 德豪 蔡, 林致遠, 梁騰云, 周芳群 and 德豪 蔡
01/07/2019

Abstract

本發明提供一種還原態觸媒的製備方法,其包含進行溶液準備步驟、進行氣霧化步驟、進行烘乾步驟、進行第一鍛燒步驟、進行還原氣體加入步驟以及進行第二鍛燒步驟。溶液準備步驟用以得到前驅物溶液。氣霧化步驟用以得到霧化液滴。烘乾步驟用以將霧化液滴自組裝成觸媒氧化前驅物。第一鍛燒步驟用以得到氧化態觸媒,第二鍛燒步驟用以得到還原態觸媒。藉此,本發明可控制樣品的氧化態,提升觸媒的催化活性、穩定性和選擇性,可有效地應用於甲烷燃燒的催化反應,以及達成二氧化碳和甲烷回收再利用之目的。 The present disclosure provides a method for fabricating a catalyst. The method includes a solution preparation step, an aerosolization step, a drying step, a first calcining step, a reducing gas addition step and a second calcining step. The solution preparation step is provided for obtaining a precursor solution. The aerosolization step is provided for obtaining an aerosolized droplet. The drying step is provided to self-assemble the aerosolized droplet into a catalyst oxidation precursor. The first calcining step is provided for obtaining an oxidation state catalyst. The second calcining step is provided for obtaining the reduction state catalyst. Accordingly, the present disclosure can control the oxidation state of the sample, improve the catalytic activity, stability and selectivity of the catalyst for effectively applying to the catalytic reaction of methane combustion, as well as effectively reutilizing CO2and methane.

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